Modification Mechanism of Polyamide Reverse Osmosis Membrane by Persulfate: Roles of Hydroxyl and Sulfate Radicals

Wei Cheng; Haodan Xu; Peizhi Wang

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Modification Mechanism of Polyamide Reverse Osmosis Membrane by Persulfate: Roles of Hydroxyl and Sulfate Radicals

机译：Modification Mechanism of Polyamide Reverse Osmosis Membrane by Persulfate: Roles of Hydroxyl and Sulfate Radicals

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Oxidative modification is a facile method to improve the desalination performance of thin-film composite membranes. In this study, we comparatively investigated the modification mechanisms induced by sulfate radical (SO4~-) and hydroxyl radical (HO*) for polyamide reverse osmosis (RO) membrane. The SO4~-_-and HO*-based membrane modifications were manipulated by simply adjusting the pH of the thermal-activated persulfate solution. Although both of them improved the water permeability of the RO membrane under certain conditions, the SO4~--modified membrane notably prevailed over the HO-modified one due to higher permeability, more consistent salt rejection rates over wide pH and salinity ranges, and better stability when exposed to high doses of chlorine. The differences of the membranes modified by the two radical species probably can be related to their distinct surface properties in terms of morphology, hydrophilicity, surface charge, and chemical composition. Further identification of the transformation products of a model polyamide monomer using high-resolution mass spectrometry demonstrated that SO4~-initiated polymerization reactions and produced hydroquinone/benzoquinone and polyaromatic structures; whereas the amide group of the monomer was degraded by HO*, generating hydroxyl, carboxyl, and nitro groups. The results will enlighten effective ways for practical modification of polyamide RO membranes to improve desalination performances and the development of sustainable oxidation-combined membrane processes.

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来源
《Environmental Science & Technology: ES&T》 |2022年第12期|8864-8874|共11页
作者
Wei Cheng; Haodan Xu; Peizhi Wang;
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作者单位

Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种英语
中图分类环境科学、安全科学;
关键词
polyamide RO membrane; oxidative modification; hydroxyl radical; sulfate radical; desalination; chlorine resistance; fouling resistance;

Modification Mechanism of Polyamide Reverse Osmosis Membrane by Persulfate: Roles of Hydroxyl and Sulfate Radicals

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