Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

Rajesham S.; Sekhar K. Chandra; Shareefuddin MdKumar J. Siva

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Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

机译：Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

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This manuscript deals with the preparation and detailed physical and structural study of B2O3-CdO-Al2O3-PbF2 glasses reinforced with MoO3 ions. With the addition of MoO3, the density and band gap values decreased while the refractive index increased, confirming the transformation of Mo6+ ions to Mo5+ ions and resulting in the generation of NBO's in these glasses. The FTIR spectra revealed the presence of different borate and aluminate units. The FTIR spectra also indicated the conversion of Mo6+ ions to Mo5+ ions. The effect of MoO3 ions on Raman spectra was clearly visible and indicated the conversion of BO4 to BO3 units, increasing NBO's which helped to explain the density variation.

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来源
《Optical and Quantum Electronics》 |2022年第8期|共13页
作者
Rajesham S.; Sekhar K. Chandra; Shareefuddin MdKumar J. Siva;
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作者单位

Osmania Univ;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);
原文格式 PDF
正文语种英语
中图分类光学;
关键词
Cadmium borate glasses; Optical absorption; Refractive index; FTIR; Raman spectra; BORATE GLASSES; FT-IR; POLARIZABILITY; OXIDES;

Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions

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