Corrosion Inhibition of Mild Steel in Sulfuric Acid by a Newly Synthesized Schiff Base: An Electrochemical, DFT, and Monte Carlo Simulation Study

Sliem Mostafa H.; El Basiony N. M.; Zaki E. G.Sharaf Mohammed A.Abdullah Aboubakr M.

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Corrosion Inhibition of Mild Steel in Sulfuric Acid by a Newly Synthesized Schiff Base: An Electrochemical, DFT, and Monte Carlo Simulation Study

机译：Corrosion Inhibition of Mild Steel in Sulfuric Acid by a Newly Synthesized Schiff Base: An Electrochemical, DFT, and Monte Carlo Simulation Study

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Effects of using a synthesized aminothiazole (BZ) Schiff base at different concentrations with and without the addition of 1 mM of KI on the corrosion mitigation of mild steel (MS) in 0.5 M sulphuric acid (H2SO4) solutions are studied electrochemically using direct and alternating currents (DC and AC) techniques. Besides, the adsorption and thermodynamic parameters are calculated in a temperature range of 293-323 K. Furthermore, Mott-Schottky analysis is used to study the type of oxide layer on the MS surface. Quantum chemical calculations and Monte Carlo simulation techniques are used, and both confirmed the experimental results.

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《Electroanalysis》 |2020年第12期|3145-3158|共14页
作者
Sliem Mostafa H.; El Basiony N. M.; Zaki E. G.Sharaf Mohammed A.Abdullah Aboubakr M.;
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作者单位

Qatar Univ, Ctr Adv Mat, POB 2713, Doha, Qatar;

Egyptian Petr Res Inst, Cairo 11727, Egypt;

Istanbul Univ Cerrahpasa, Dept Maritime Transportat Management Engn, TR-34320 Istanbul, Turkey;

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正文语种英语
中图分类电化学、电解、磁化学;
关键词
Mild steel; Corrosion; Inhibition; potential of zero charge (PZC); Monte Carlo simulation;

Corrosion Inhibition of Mild Steel in Sulfuric Acid by a Newly Synthesized Schiff Base: An Electrochemical, DFT, and Monte Carlo Simulation Study

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