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Stabilization of high‐density polyethylene

机译:Stabilization of high‐density polyethylene

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AbstractSeveral types of antioxidants are evaluated in high‐density polyethylene for color and physical property stabilization during processing and thermal aging. A wide variety of evaluation tests are used and discussed. Heat‐ and light‐induced oxidation mechanisms are reviewed. Antioxidants such as octadecyl‐3‐(3,5‐di‐tert‐butyl‐4‐hydroxyphenyl) propionate and tetrakismethylene 3‐(3′,5′‐di‐tert‐butyl‐4′‐hydroxy phenyl) propionate methane were found to provide very high retention of physical properties, excellent initial color and color retention. Combinations of antioxidant‐ and ultraviolet light absorbers were evaluated for stabilizing high density polyethylene exposed to artificial light and outdoor weathering. The combination of octadecyl‐3‐(3,5‐di‐tert‐butyl‐4‐hydroxyphenyl) propionate and 2‐(2′‐5′‐di‐tert‐butyl‐2′‐hydroxy‐phenyl)‐5‐chlorobenzotriazole was found to be a very efficient stabilizer system. Polymer containing this stabilizer combination had excellent colo

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