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Raman scattering and X-ray diffraction study in Cu2GeSe3

机译:Raman scattering and X-ray diffraction study in Cu2GeSe3

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摘要

A combined Study of X-ray diffraction data and micro-Raman scattering of Cu2GeSe3 is presented. From the analysis of the X-ray data it is confirmed that this compound crystallizes in an orthorhombic cell, space group I mm2. From Raman spectra, optical modes are identified and their possible symmetry assignments are suggested. Peaks at 212, 266 and 300 cm(-1), tentatively assigned to B-2 modes, agree well with those reported front infrared reflectivity. The most strong peak at 189 cm(-1) which is only Raman active is assigned to one of the two A(2) modes. Lines at 135, 235 and 254 cm(-1) probably comprises the are attributed to A(1) or B-1 modes. The highest phonon frequency hand, observed at 385 cm(-1) remaining A(2) mode and an overtone from the strong line at 189 cm(-1). (c) 2008 Elsevier Ltd. All rights reserved.

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