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Some analogies in the mechanical behavior of filled polymers

机译:Some analogies in the mechanical behavior of filled polymers

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AbstractThe temperature and frequency dependences of complex shear modulus and mechanical losses were studied for expoxy resin composition in the presence of different amounts of quartz and polystyrene fillers. The data obtained were analyzed by the use of the Williams‐Landell‐Ferry method. It was shown that in the mechanical behavior of filled polymers, except for the well‐known temperature‐time analogy there exist some lows connected with the presence of filler. The change in filler concentration leads to the same change in the real part of complex modulus as change in frequency (concentration–time analogy), and change in temperature is equivalent to concentration change (temperature–concentration analogy). The existence of these analogies is explained by a change in deformation conditions for polymeric matrix in the presence of different amount of filler, by the existence of surface layers of polymer at the interface with solid filler, and by peculiarities of the mechanical behavior of filler. It is also established that the thickness of surface layer which was determined from experimental data depends on temperature and has an extremum in the temperature region of the

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