首页>
外文期刊>journal of applied polymer science
>New aspects in cationization of lignocellulose materials. III. Influence of delignification on reactivity and extractability of TMAHP–hemicelluloses
【24h】
New aspects in cationization of lignocellulose materials. III. Influence of delignification on reactivity and extractability of TMAHP–hemicelluloses
展开▼
机译:New aspects in cationization of lignocellulose materials. III. Influence of delignification on reactivity and extractability of TMAHP–hemicelluloses
AbstractBeech sawdust samples with different lignin content were alkylated with 3‐chloro‐2‐hydroxypropyltrimethylammoniumchloride (CHMAC). The yields and the degree of subtitution of trimethylammonium‐2‐hydroxypropyl (TMAHP) samples were similar. Differences were found in extractability of hemicelluloses from this materials both with water and dilute alkali. To obtain the maximum yield of TMAHP–hemicelluloses (ca. 90 of the amount originally present), it is sufficient to remove about 50 of lignin. The lignin component does not influence the reactivity of hemicelluloses. The isolated hemicelluloses differ only in the distribution of functional groups and ext
展开▼