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>Single crystal EPR of studies Ni(II) in hexaimidazole zinc (II)dichloride tetrahydrate: a case of rhombic distortion
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Single crystal EPR of studies Ni(II) in hexaimidazole zinc (II)dichloride tetrahydrate: a case of rhombic distortion
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机译:Single crystal EPR of studies Ni(II) in hexaimidazole zinc (II)dichloride tetrahydrate: a case of rhombic distortion
Single crystal electron paramagnetic resonance of Ni(II) doped hexaimidazole zinc(II)dichloride tetrahydrate has been studied at room temperature. The material exhibited rhombic g and D tensors. The spin Hamiltonian parameters obtained from single crystal rotations are g(11)=2.3691, g(22)=2.2105, g(33)=1.9409 and D-11=244.07, D-22=24.98, D-33=-269.05 mT. It has been inferred that Ni(II) replaces zinc(II) substitutionally. (C) 2002 Elsevier Science Ltd. All rights reserved. References: 11
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