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>Polymerization of olefins through heterogeneous catalysis. II. Kinetics of gas phase propylene polymerization with Ziegler–Natta catalysts
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Polymerization of olefins through heterogeneous catalysis. II. Kinetics of gas phase propylene polymerization with Ziegler–Natta catalysts
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机译:Polymerization of olefins through heterogeneous catalysis. II. Kinetics of gas phase propylene polymerization with Ziegler–Natta catalysts
AbstractPropylene was polymerized in gas phase over adocumentclass{article}pagestyle{empty}begin{document}${rm TiCl}_3 cdot frac{1}{3}{rm AlCl}_3$end{document}(Stauffer Type AA) Catalyst with AlEt2Cl cocatalyst both with and without H2present. The effects of polymerization temperature, monomer concentration, catalyst composition, and hydrogen were investigated. The experiments were carried out at operating conditions approaching industrial practice.
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