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首页> 外文期刊>journal of applied polymer science >Preparation of polymeric initiators of the anionic polymerization of lactams from polyetherdiols
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Preparation of polymeric initiators of the anionic polymerization of lactams from polyetherdiols

机译：Preparation of polymeric initiators of the anionic polymerization of lactams from polyetherdiols

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AbstractThe kinetics of alcoholysis of bis(N‐acyl‐6‐hexanelactams) and bis(N‐carbamoyl‐6‐hexanelactams) was studied for the purpose of the preparation of bifunctional polymeric initiators of the anionic polymerization of 6‐hexanelactam used in the production of polyamide block copolymers by reactive processing. The reaction was carried out with 1‐octanol as a model alcohol and with poly(propylene oxide)diol, without catalysis or using anionic and polyesterification catalysts, and in 6‐hexanelactam as a solvent. Applicability of this functionalization method is discussed with respect to a broad spectrum of formed products, competition of lactam oligomerization in the presence of basic catalysts, preparation of the initiator component for two‐component polymerization systems, andin situfunctionalization during polymerization. © 1992

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