• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>journal of applied polymer science >Thermal behavior and morphology of rubber‐modified epoxies
【24h】

Thermal behavior and morphology of rubber‐modified epoxies

机译：Thermal behavior and morphology of rubber‐modified epoxies

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相关主题

摘要

AbstractRubber‐modified epoxies of tetraglycidyl‐4,4′‐diaminodiphenyl methane and a carboxylterminated copolymer of butadiene–acrylonitrile (CTBN) have been investigated by differential scanning calorimetry, scanning electron microscopy, and micrograph image analysis. Bisphenol‐A (BPA) was used to produce chain‐extended resins by reaction with the epoxy‐terminated rubber. Diaminodiphenyl sulfone was used as a hardener. Partially cured resins were prepared with different amounts of added CTBN and cured in an oven for different cure times at 448 K. From the measured heat of reaction of the samples, a fast curing reaction was observed when BPA was present in the resin formulation. In the study of the morphology, the average size of the domains was seen to increase with the CTBN content. These CTBN‐rich domains appear to include substantial amounts of epoxy material, as indicated by the measured glass transition temperature of the CTBN‐rich phase. The size of domains was observed to range mostly from 0.1 to 5 μm in diameter and to show a slightly bimodal distribution, with modes around 1 μm and 3–4 μm when 15 and 20 phr CTBN was added. ©

著录项

获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号