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>Ionic graft copolymerization. IV. Polymerization of β‐propiolactone by acetic acid,p‐toluenesulfonic acid, and their sodium salts
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Ionic graft copolymerization. IV. Polymerization of β‐propiolactone by acetic acid,p‐toluenesulfonic acid, and their sodium salts
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机译：Ionic graft copolymerization. IV. Polymerization of β‐propiolactone by acetic acid,p‐toluenesulfonic acid, and their sodium salts
AbstractAcetic acid, toluenesulfonic acid, and their salts are used as four representative ionic catalysts for polymerization of β‐propiolactone (βPL). They are classified as follows: sodium acetate is an anionic catalyst, acetic acid is a neutral one having more covalent character, sodium toluene sulfonate is a neutral one having more ionic character, toluenesulfonic acid is a cationic one. The neutral catalyst having more covalent nature is hardly dissociated, and therefore the rate of polymerization is quite small; however, dissociated ions consist of a higher neucleophilic anion and a higher electrophilic cation. On the contrary, the neutral catalyst having an ionic bond dissociates more easily, but the formed ions consist of the less reactive anion and cation. Therefore, it is of interest whether β‐propiolactone is polymerized by a cationic mechanism or an anionic mechanism by these catalysts. The mechanisms of polymerizations of βPL by these neutral catalysts were studied on the basis of the different behaviors of polymerizations by the four catalysts described above. In the cationic polymerization by toluenesulfonic acid, the rate of polymerization was high, but the conversion reaches a low, limited value. In the anionic polymerization by sodium acetate, the rate of polymerization was high and the degree of polymerization of polymer was the highest. Acetic acid has the lowest catalyst activity and the degree of polymerization is also very small. It was found that the polymerization by sodiump‐toluenesulfonate was accelerated in the presence of acrylic acid produced from βPL by hydrogen‐trans
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