Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

Emma C. Harvey; Ben L. Feringa; Johannes G. VosWesley R. BrowneMary T. Pryce

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Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

机译：Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

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In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed. A key challenge in designing such systems is to allow for interaction between the various components, but without loss in photochemical activity, i.e. the cyclization/cycloreversion of the dithienylethene unit. Examples of where the properties of the switching unit can be fine-tuned either photochemically or electrochemically by the addition of either bipyridyl transition metals or organometallic moieties to the switch will be highlighted.

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来源
《Coordination chemistry reviews》 |2015年第1期|77-86|共10页
作者
Emma C. Harvey; Ben L. Feringa; Johannes G. VosWesley R. BrowneMary T. Pryce;
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作者单位

Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4,9747 AG Groningen, The Netherlands;

School of Chemical Sciences, Dublin City University, Dublin 9, Ireland;

School of Chemical Sciences, Dublin City University, Dublin 9, Ireland,Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4,9747 AG Groningen, The Netherlands;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类无机化学;
关键词
Dithienylcyclopentene; Transition metals; Photocyclisation; Electrochromism; NLO;

Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

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