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Thermally stimulated current of iodine‐doped acrylonitrile–butadiene–styrene thin films

机译:Thermally stimulated current of iodine‐doped acrylonitrile–butadiene–styrene thin films

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AbstractStructural change of acrylonitrile–butadiene–styrene (ABS) terpolymer due to iodine doping has been reported using both infrared (IR) and thermally stimulated current (TSC) techniques. IR investigation revealed the presence of a new stretching band at 640 cm−1that indicates the formation of the C‐I structure. The TSC spectrum consists of two different decaying charge distributions of opposite polarity, which simply superpose to yield the net current observed. The variation of the position of the negative peak relaxation and its intensity as the iodine percentages increases indicates the formation of different ionic iodine species. The induced ionic dipoles superpose the α‐relaxation of ABS. © 1993 John Wile

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