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>Crystal structure ofcis-Ru(bpy)2{PPh2(o-tol)}ClClO4·1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization
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Crystal structure ofcis-Ru(bpy)2{PPh2(o-tol)}ClClO4·1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization
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机译：Crystal structure ofcis-Ru(bpy)2{PPh2(o-tol)}ClClO4·1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization
The complexcis-Ru(bpy)2{PPh2(o-tol)}ClClO4 crystallizes from dichloromethane as the sesqui-dichloromethane solvate. The complex crystallizes in the monoclinic space group P21/n with Z=4. The structure was refined toR=5.50 for those 2552 independent reflections with F0>6σ(F0) The octahedral Ru(II) cation is associated with the following bond lengths: Ru-PPh2(o-tol)=2.360(3)Å. Ru−Cl=2.433(2)Å and Ru−N(bpy)=2.041(8)–2.095(8)Å. Both the perchlorate anion and the dichloromethane molecules of solvation exhibit large amplitudes of vibration. One dichloromethane molecule lies in a general position, the other lies about an inversion center and suffers from
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