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Synthesis and photoconductivity study of phthalocyanine polymers. III. PVK‐CuPC(NO2)2

机译:Synthesis and photoconductivity study of phthalocyanine polymers. III. PVK‐CuPC(NO2)2

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AbstractCu‐dinitro‐diamine phthalocyanine was synthesized, the corresponding diazonium salt was reacted with vinylcarbazole (VK), and a novel polyvinylcarbazole (PVK) ‐bonded CuPc(NO2)2(I) was synthesized. The chemical structure of polymer (I) is identified by elemental analysis and IR and UV / VIS spectroscopy. Polymer (I) contains about 21 mol CuPc(NO2)2rings that are covalently bonded to PVK. Polymer (I) shows good pho‐toconductivity, which is much better than that of the corresponding phthalocyanine monomers. The influence of the interface layer and the charge‐transportation material on the photoconductivity of polymer (I) is also discussed. © 1993 John Wiley

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