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Relationships between mechanical properties and relaxation processes in polymers. Nylon 6

机译:Relationships between mechanical properties and relaxation processes in polymers. Nylon 6

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AbstractThe dynamic‐mechanical properties as a function of temperature and frequency were measured for five samples of polycaprolactam (nylon 6) containing different amounts of hydrosoluble products. Low‐ and high‐speed tensile properties and Izod impact strength were determined between −190° and 100°C for the same samples by using autographic methods. The influence of the mechanical relaxation processes on moduli, yield strength σy, yield strain εy, tough‐brittle transition temperature, elongation at break εR, and tensile and Izod fracture energies was investigated. It has been found that some mechanical properties, such as modulus and yield properties, can be directly related to specific relaxation phenomena, whereas as far as other properties, such as the ultimate properties, are concerned, the existing correlation can be concealed by the interference of purely mechanical phenomena which depend on the testing technique used, the testing conditions, and the previous history o

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