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FeCl_3-Based Few-Layer Graphene Intercalation Compounds: Single Linear Dispersion Electronic Band Structure and Strong Charge Transfer Doping

机译:FeCl_3-Based Few-Layer Graphene Intercalation Compounds: Single Linear Dispersion Electronic Band Structure and Strong Charge Transfer Doping

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摘要

Craphene has attracted much attention since its first discovery in 2004. Various approaches have been proposed to control its physical and electronic properties. Here, it is reported that graphene-based intercalation is an efficient method to modify the electronic properties of few-layer graphene (FLC). FeCl_3 intercalated FLCs are successfully prepared by the two-zone vapor transport method. This is the first report on full intercalation for graphene samples. The features of the Raman C peak of such FLC intercalation compounds (FLCIC) are in good agreement with their full intercalation structures. The FLCICs present single Lorentzian 2D peaks, similar to that of single-layer graphene, indicating the loss of electronic coupling between adjacent graphene layers. First principle calculations further reveal that the band structure of FLCIC is similar to single-layer graphene but with a strong doping effect due to the charge transfer from graphene to FeCl_3. The successful fabrication of FLCIC opens a new way to modify properties of FLC for fundamental studies and future applications.

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