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>Pyrolysis and combustion of cellulose. VIII. Thermally initiated reactions of phosphonomethyl amide flame retardants
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Pyrolysis and combustion of cellulose. VIII. Thermally initiated reactions of phosphonomethyl amide flame retardants
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机译：Pyrolysis and combustion of cellulose. VIII. Thermally initiated reactions of phosphonomethyl amide flame retardants
AbstractSeveralN‐(phosphonomethyl) amides have previously been reported to act as particularly effective flame retardants for cellulose. It has also been demonstrated previously that the efficiency of a flame retardant on cellulose frequently parallels its ability to phosphorylate cellulosic hydroxyls at elevated temperatures. This study of the hydrolysis and alcoholysis reactions ofN‐(phosphonomethyl) amides establishes their unique reactivity. An explanation for this high reactivity is proposed on the basis of intramolecular assistance of the attack of water or alcohols at phosphorus by the carbonyl oxygen of the amide moi
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