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Studies of relaxation phenomena in polymers. II. The behavior of simple polymers in their main transition region

机译:Studies of relaxation phenomena in polymers. II. The behavior of simple polymers in their main transition region

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AbstractIn an earlier paper, a “new” viscoelastic function, logJ2=g{logJ1}, was defined. For polymers, the linear viscoelastic behavior of which is characterized by “simple segment movements” in their main transition regions, the following general properties are found: (1) The local maxima of the function for different polymers fall along a straight line width the slope approximately equal to 1.1. (2) A characteristical general shape is noticed for the function after shifting along the straight line and reducing theJ1compliance as regards the “frozen in” complianceJ10. (3)J1reflects the storage andJ2, the loss mechanisms of the system. The relationJ2/J1is an expression for the average retar

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