Formation of Nanostructures Based on Nickel Complexes with the Assistance of h-bonds on the modified silicon surfaces

L. I. Matienko; V. I. Binyukov; L. A. MosolovaE. M. MilG. E. Zaikov

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Formation of Nanostructures Based on Nickel Complexes with the Assistance of h-bonds on the modified silicon surfaces

机译：Formation of Nanostructures Based on Nickel Complexes with the Assistance of h-bonds on the modified silicon surfaces

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The role of the intermolecular H-bonds in mechanisms of catalysis of with polynuclear hetero ligand complexes M(Ⅱ)_xL~1 _y(L~1_(ox))_z(L~2)_n(H_2O)_m (m=nj, Fe, L~1 = acac~-, L~1_(ox) = CH_3COO~-, L~2 = R_4NBr, 18C6, MP (N-methylpirrolidon-2, m=ni)) as active catalysts of alkylarens oxidation to corresponding hydroperoxides and as models of Ni(Fe)ARE) dioxygenases, is discussed. The AFM method has been used for research of possibility of the stable supramolecular structures formation on the basis of nickel complexes M(Ⅱ)_xL~1_y(L~1_(ox)_z(L~2)_n(H_2O)_m("A"), (Ni_2(AcO)_3(acac)MP?2H_2O, M-Ni. L~1 = acac~-, L~1_(ox) = CH_3COO , L~2 = MP = N-methylpirrolidon-2, x=2, y=l, z=3, n=l, m=2) with the assistance of intermolecular H-bonds.

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来源
《International journal of planning and scheduling》 |2014年第2期|93-103|共11页
作者
L. I. Matienko; V. I. Binyukov; L. A. MosolovaE. M. MilG. E. Zaikov;
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N.M. Emanuel Institute of Biochemical Physics Russian Academy of Sciences Moscow, Russian Federation;

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正文语种英语
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nanostructures; Ni_2(OAc)_3(acac)MP?2H_2O (MP=N-methylpirrolidon-2); H-bonds; catalysis; ethylbenzene; oxidation; dioxygen; models of Ni(Fe)ARD dioxygenases;

Formation of Nanostructures Based on Nickel Complexes with the Assistance of h-bonds on the modified silicon surfaces

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