NaScBP2O6(OH)(3)(HO)PO3: Synthesis and Crystal Structure of an Alkali-Metal Scandium Borophosphate Hydrogenphosphate

Menezes PW; Hoffmann S; Prots YKniep R

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NaScBP2O6(OH)(3)(HO)PO3: Synthesis and Crystal Structure of an Alkali-Metal Scandium Borophosphate Hydrogenphosphate

机译：NaScBP2O6（OH）（3）（HO）PO3：碱金属硼磷酸氢钪的合成及晶体结构

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摘要

The compound NaScBP2O6(OH3(HO)PO3 was prepared under mild hydrothermal conditions. The crystal structure was determined from single crystal X-ray data: monoclinic, space group P2(1)/c (No. 14), a = 5.0010(1) angstrom, b = 12.4271(9) angstrom, c = 15.8340(14) angstrom, beta = 94.201(4), V = 981.41 (11) angstrom(3) and Z = 2. The crystal structure comprises of isolated borophosphate oligomers, BP2O6(OH)(3)(2-), and isolated hydrogenphosphate groups, (HO)PO3(2-) which are interconnected by ScO6 coordination octahedra by sharing common corners. The resulting three-dimensional framework is characterized by channels running along 100 forming, four-, six-, and twelve-membered rings. Sodium ions reside within the six-membered ring channels.

机译：在温和的水热条件下制备了化合物NaSc[BP2O6（OH3][（HO）PO3]。根据单晶X射线数据确定晶体结构：单斜晶系，空间群P2（1）/c（14号），a=5.0010（1）埃，b=12.4271（9）埃，c=15.8340（14）埃，β=94.201（4），V=981.41（11）埃（3），Z=2。晶体结构由分离的硼磷酸盐低聚物[BP2O6（OH）（3）]（2-）和分离的磷酸氢基团[（HO）PO3]（2-）组成，它们通过共享共角通过ScO6配位八面体相互连接。由此产生的三维框架的特征是沿[100]形成的四元环、六元环和十二元环运行的通道。钠离子位于六元环通道内。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2010年第1期|19-22|共4页
作者
Menezes PW; Hoffmann S; Prots YKniep R;
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作者单位

Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany.;

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原文格式 PDF
正文语种英语
中图分类化学;
关键词
Hydrothermal synthesis; Boron; Borophosphate; Hydrogenphosphate; Scandium;

机译：水热合成;硼;硼磷酸盐;磷酸氢盐;钪;

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1. NaSc[BP2O6(OH)(3)][(HO)PO3]: Synthesis and Crystal Structure of an Alkali-Metal Scandium Borophosphate Hydrogenphosphate [J] . Menezes PW, Hoffmann S, Prots Y, Zeitschrift fur Anorganische und Allgemeine Chemie . 2010,第1期

机译：NaSc [BP2O6（OH）（3）] [（HO）PO3]：碱金属硼磷酸Scan磷酸氢盐的合成与晶体结构
2. Synthesis and crystal structure of thorium bis(hydrogenphosphate) monohydrate [J] . Salvado MA, Pertierra P, Castro GRTrobajo CGarcia JR Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第4期

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机译：Hybrid open frameworks. 8. Hydrothermal synthesis, crystal structure, and thermal behavior of the first three-dimensional titanium(IV) diphosphonate with an open structure: Ti3O2(H2O)(2)(O3P-(CH2)-PO3)(2)center dot(H2O)(2), or MIL-22
4. NaScBP2O6(OH)3(HO)PO3: synthesis and crystal structure of the first alkali metal scandium borophosphate hydrogenphosphate [O] . Stefan Hoffmann, Prashanth Wilfred Menezes, Yurii Prots, 2009

机译：NASC BP2O6（OH）3 （HO）PO3：第一碱金属钪磷酸硅磷酸钪的合成和晶体结构

NaScBP2O6(OH)(3)(HO)PO3: Synthesis and Crystal Structure of an Alkali-Metal Scandium Borophosphate Hydrogenphosphate

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