Using Pd as a Cocatalyst on GaN-ZnO Solid Solution for Visible-Light-Driven Overall Water Splitting

Li Zheng; Zhang Fuxiang; Han JingfengZhu JianLi MingrunZhang BingqingFan WenjunLu JunlingLi Can

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Using Pd as a Cocatalyst on GaN-ZnO Solid Solution for Visible-Light-Driven Overall Water Splitting

机译：Using Pd as a Cocatalyst on GaN-ZnO Solid Solution for Visible-Light-Driven Overall Water Splitting

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Rhodium was reported to be an essential component of the efficient cocatalyst (Rh2-xCrxO3 or core/shell of Rh@Cr2O3) on GaN-ZnO for photocatalytic overall water splitting (POWS). Herein we demonstrate that the Rh can be replaced by less-expensive Pd deposited via atomic layer deposition and together with photodeposition of Cr2O3 shell, a comparable activity in POWS can be achieved even with much less Pd loading than Rh in Rh2-xCrxO3/GaN-ZnO under the same reaction conditions.

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来源
《Catalysis Letters》 |2018年第3期|933-939|共7页
作者
Li Zheng; Zhang Fuxiang; Han JingfengZhu JianLi MingrunZhang BingqingFan WenjunLu JunlingLi Can;
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作者单位

Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy,iChEM, Dalian 116023, Peoples R China;

Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Mat Energy Convers, CAS Ctr Excellence Nanosci,Dept Chem Phys,iChEM, Hefei 230026, Anhui, Peoples R China;

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正文语种英语
中图分类催化;
关键词
Photocatalysis; Cocatalyst; Overall water splitting; GaN-ZnO; ALD;

Using Pd as a Cocatalyst on GaN-ZnO Solid Solution for Visible-Light-Driven Overall Water Splitting

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