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Variation of refractive index of polystyrene with molecular weight: Effect on the determination of molecular weight distributions
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机译:Variation of refractive index of polystyrene with molecular weight: Effect on the determination of molecular weight distributions
AbstractSensitive refractive index measurements on solutions have indicated that the narrow molecular weight polystyrene samples prepared by the Mellon Institute method exhibit a small systematic molecular weight–refractive index dependence up to 300,000 and higher. This upper limit is higher than had previously been suggested. Sensible consistency is generally assumed above a few thousand molecular weight. The effect on this molecular weight–refractive index dependence on gel permeation chromatography and light‐scattering molecular weight measurements on polystyrene standards is illust
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