Adsorption and desorption of dieldrin and lindane on chitin were investigated in seawater batch tests as a function of chitin concentration, temperature, pH and salinity. For chitin concentrations ranging from 0.5 g l#x2212;1to 12.5 g l#x2212;1, the pesticide concentrations were varied from 4 #x3BC;gl#x2212;1to 65 #x3BC;g#x2212;1for dieldrin and from 40 #x3BC;l#x2212;1to 680 #x3BC;g l#x2212;1for lindane. Both dieldrin and lindane show adsorption-desorption hysteresis at low chitin concentration. At high chitin concentrations (m 6.25 g l#x2212;1for dieldrin andm 10 gl#x2212;1for lindane) both pesticides exhibit reversible behaviour. However, only lindane adsorption is affected by chitin concentration. These types of behaviour remain fixed in prewashed chitin. However, an increase in the temperature and a decrease in the salinity made the process become reversible. A resistant-reversible two component model has been applied to account for these types of behaviour and provides a way to explain most of the observed effects by defining mass independent distribution coefficients.
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