In-Situ Compositional and Structural Analysis of Plastic Solar Cells

Jeroen K. J. van Duren; Joachim Loos; Francis MorrisseyChristian M. LeewisKoen P. H. KivitsLeo J. van IJzendoornMinze T. RispensJan C. HummelenRene A. J. Janssen

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In-Situ Compositional and Structural Analysis of Plastic Solar Cells

机译：In-Situ Compositional and Structural Analysis of Plastic Solar Cells

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Bulk-heterojunction photovoltaic cells consisting of a photoactive layer of poly2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylenevinylene (MDMO-PPV) and a C_(60) derivative, (1-3-methoxycarbonyl)propyl-1-phenyl-6,6-methanofullerene), (PCBM), sandwiched between an indium tin oxide (ITO) anode covered with poly(ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), and an aluminum cathode have been analyzed using transmission electron microscopy (TEM) and cryogenic Rutherford backscattering spectrometry (RBS) to assess the structural and elemental composition of these devices. TEM of cross sections of fully processed photovoltaic cells, prepared using a focused ion beam, provide a clear view of the individual layers and their interfaces. RBS shows that during preparation diffusion of indium into the PEDOT:PSS occurs while the diffusion of aluminum into the polymer layers is negligible. An iodinated C_(60) derivative (I-PCBM) was used to determine the concentration profile of this derivative in the vertical direction of a 100 nm active layer.

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《Advanced functional materials》 |2002年第10期|665-669|共5页
作者
Jeroen K. J. van Duren; Joachim Loos; Francis MorrisseyChristian M. LeewisKoen P. H. KivitsLeo J. van IJzendoornMinze T. RispensJan C. HummelenRene A. J. Janssen;
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Laboratory of Macromolecular and Organic Chemistry Eindhoven University of Technology P.O. Box 513, NL-5600 MB Eindhoven (The Netherlands);

Eindhoven Polymer Laboratories and Dutch Polymer Institute Eindhoven University of Technology P.O. Box 513, NL-5600 MB Eindhoven (The Netherlands);

FEI company P.O. Box 80066, NL-5600 KA Eindhoven (The Netherlands)Centre for Plasmaphysics and Radiation Technology Department of Applied Physics, Eindhoven University of Technology P.O. Box 513, NL-5600 MB Eindhoven (The Netherlands)Stratingh Institute and Materials Science Centre, University of Groningen Nijenborgh 4, NL-9747 AG Groningen (The Netherlands);

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中图分类无线电电子学、电信技术;
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In-Situ Compositional and Structural Analysis of Plastic Solar Cells

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