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Studies on the preparation and properties of conductive polymers. IV. Novel method to prepare metallized plastics from metal chelates of polymides–imides

机译:Studies on the preparation and properties of conductive polymers. IV. Novel method to prepare metallized plastics from metal chelates of polymides–imides

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AbstractA new type of polyamide–imides (PAI) was synthesized by direct polycondensation. A series of polyamide–imide metal chelate films was prepared by the transition‐metal salts (AgNO3, CuCl2, and CoCl2) mixed with the polyamide–imides in NMP solution. These polyamide–imide metal chelate films were reduced by various reducing agents, and the reduced films exhibited low surface resistivity around 100−101Ω/cm2. The surfaces of these conductive films were proved to be metallized by means of X‐ray analysis. The metal adhered on the film was believed to be responsible for the improvement of electrical conductivity. The effects of kinds and concentrations of metal salts, kinds and concentrations of reducing agents, and reduction time on the conductivity of metallized films were investigated. The IR spectra and SEM observations of unreduced and reduced polymer chelate films wer

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