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Synthesis and properties of an easy‐processable bismaleimide thermoset resin

机译:Synthesis and properties of an easy‐processable bismaleimide thermoset resin

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AbstractReaction of methylenedianiline and maleic anhydride in acetone, followed by cyclodehydration in the presence of acetic anhydride and 1,4‐diazabicyclo 2.2.2 octane as a catalyst, affords a mixture of compounds, Desbimid, with maleimide, isomaleimide, and acetamide groups. Dissolution of this mixture in styrene and 2‐hydroxyethyl methacrylate results in clear liquid resins. The viscosity of the formulated resins ranges from 100–1700 mPas at 25°C depending on the concentration of Desbimid. These systems can be processed and cured at ambient temperatures until demoulding and postcured at temperatures up to 200 or 250°C. The flexural modulus, flexural strength, and elongation at break of a number of cured formulations are found between 3500–3800 N/mm2, 90–115 N/mm2, and 2.7–3.5,

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