Crystals of Co(C5H4COOMe)2(PF6) are triclinic, spacegroup$$Pbar 1$$witha=6.854(3),b=7.367(4),c=9.430(4) Å, α=69.12(3), β=86.56(4), γ=67.20(4)°,Z=1. The cation and anion both lie on crystal inversion centers. The Co−C bond lengths are in the range 2.030–2.041(3) Å. The COOMe groups are twisted 5.4° from the cyclopentadienyl ring planes. Refinement with 1574 data I>3σ(I) converg
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