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Enhanced ferroelectric, magnetic and magnetoelectric properties of Bi 1-xCaxFe1-xTixO3 solid solutions

机译:Enhanced ferroelectric, magnetic and magnetoelectric properties of Bi 1-xCaxFe1-xTixO3 solid solutions

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摘要

We report on the enhanced electromechanical, magnetic and magnetoelectric properties of Bi_(1-x)Ca_xFe_(1-x)Ti_xO _3 solid solutions. The crystal structure of the x≈0.25 compounds are close to the rhombohedralorthorhombic phase boundary, and the solid solutions are characterized by increased electromechanical properties due to the polarization extension near the polarnonpolar border. The homogenous weakly ferromagnetic state is established at x>0.15 doping. The chemical doping shifts the magnetic transition close to room temperature, thus enlarging the magnetic susceptibility of the compounds. The solid solutions at the morphotropic phase boundary exhibit a nearly twofold increase in piezoelectric response, whereas the magnetoelectric coupling shows five times enhancement in comparison with the parent bismuth ferrite.

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