首页>
外文期刊>journal of chemical crystallography
>Synthesis and base promoted intramolecular nucleophilic reaction of 8-hydroxy-1,2,3,4-tetrachloro-9,9-dimethoxy-1α,4α,4aα,6,7,8β,8aα-hexahydro-1,4-methanonaphthalene-5(1H)-one
【24h】
Synthesis and base promoted intramolecular nucleophilic reaction of 8-hydroxy-1,2,3,4-tetrachloro-9,9-dimethoxy-1α,4α,4aα,6,7,8β,8aα-hexahydro-1,4-methanonaphthalene-5(1H)-one
展开▼
机译:Synthesis and base promoted intramolecular nucleophilic reaction of 8-hydroxy-1,2,3,4-tetrachloro-9,9-dimethoxy-1α,4α,4aα,6,7,8β,8aα-hexahydro-1,4-methanonaphthalene-5(1H)-one
Catalytic hydrogenation of two substituted hexahydro-1,4-dimethanonaphthalene-5,8-diones results in reduction of the enedione carbon-carbon double bond with concomitant reduction of only one of the two chemically equivalent C=O groups. Reaction of one partially reduced product with base results in intramolecular addition to the carbon-carbon double bond.
展开▼