Acidic Activated Carbons: An Efficient Catalyst for the Epoxide Ring-Opening Reaction with Ethanol

Carlos J. Duran-Valle; Jesus A. Garcia-Vidal

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Acidic Activated Carbons: An Efficient Catalyst for the Epoxide Ring-Opening Reaction with Ethanol

机译：Acidic Activated Carbons: An Efficient Catalyst for the Epoxide Ring-Opening Reaction with Ethanol

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The epoxides (styrene oxide and 1,2-epoxy-hexane) reaction with ethanol was carried out, catalysed with acidic activated carbons. The reactions were carried out under microwave irradiation. In the 1,2-epoxyhexane reaction, high yields were attained in some of the reaction conditions tested, although the regioselectivity was not high. For the styrene oxide reaction, the conversion was higher and the regioselectivity was high in most cases. For comparison, the reactions have been also performed in a batch reactor system under thermal activation.

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来源
《Catalysis Letters》 |2009年第2期|37-41|共5页
作者
Carlos J. Duran-Valle; Jesus A. Garcia-Vidal;
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作者单位

Departamento de Quimica Organica e Inorganica, Universidad de Extremadura, Avda. de Elvas s/n, E-06071, Badajoz, Spain;

Departamento de Quimica Organica e Inorganica, Universidad de Extremadura, Avda. de Elvas s/n, E-06071, Badajoz, Spain;

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正文语种英语
中图分类化学工业;
关键词
Acidic carbons; Microwave irradiation; Epoxides; Ring-opening; Catalysis;

Acidic Activated Carbons: An Efficient Catalyst for the Epoxide Ring-Opening Reaction with Ethanol

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