The triolein-filled semipermeable membrane device (SPMD) is a simple and effective method of assessing the presence of waterborne hydrophobic chemicals. Uptake rate constants for individual chemicals are needed to accurately relate the amounts ofchemicals accumulated by the SPMD to dissolved water concentrations. Brown trout and SPMDs were exposed to PCB-contaminated groundwater in a spring for 28 days to calculate and compare uptake rates of specific PCB congeners by the two matrixes. Total PCBcongener concentrations in water samples from the spring were assessed and corrected for estimated total organic carbon (TOC) sorption to estimate total dissolved concentrations. Whole and dissolved concentrations averaged 4.9 and 3.7μg/L, respectively,during the exposure. Total concentrations of PCBs in fish rose from 0.06 to 118.3 μg/g during the 28-day exposure, while concentrations in the SPMD rose from 0.03 to 203.4μg/g. Uptake rate constants (K{sub}1) estimated for SPMDs and brown trout werevery similar, with k1 values for SPMDs ranging from one to two times those of the fish. The pattern of congener uptake by the fish and SPMDs was also similar. The rates of uptake generally increased or decreased with increasing K{sub}ow, depending on theassumption of presence or absence of TOC.
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