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Multiferroic and magnetoelectric nature of GaFeO _3, AlFeO _3 and related oxides

机译:Multiferroic and magnetoelectric nature of GaFeO _3, AlFeO _3 and related oxides

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摘要

GaFeO _3, AlFeO _3 and related oxides are ferrimagnetic exhibiting magnetodielectric effect. There has been no evidence to date for ferroelectricity and hence multiferroicity in these oxides. We have investigated these oxides as well as oxides of the composition Al _(1-x-y)Ga xFe _(1y)O _3 (x=0.2, y=0.2) for possible ferroelectricity by carrying out pyroelectric measurements. These measurements establish the occurrence of ferroelectricity at low temperatures below the Nèel temperature in these oxides. They also exhibit significant magnetoelectric effect. We have tried to understand the origin of ferroelectricity based on non-centrosymmetric magnetic ordering and disorder by carrying out first-principles calculations.

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