A particle trap impactor/denuder system has been developed and tested for the sampling of ambient carbonaceous aerosols. Use of a particle trap impactor allows for a reduction of particle bounce and re-entrainment at high particle loadings, and operation at high volumetric flow rates is achieved without the use of oiled impaction substrates, thus facilitating the chemical and physical analysis of the organic compounds comprising the collected gas (G) and particle (P) phases. Honeycomb denuders have a greater density of channels for a given denuder cross-sectional area than parallel plate or annular denuders; for a given sampling flow rate, honeycomb denuders can be fabricated in more compact shapes and will have a greater amount of surface area for the collection of gases. Field testing of the sampler was conducted primarily at night to minimize the evaporation of organic carbon (OC) from collected particles, which can result from the heating of collected particles as ambient temperatures rise during the day. In side-by-side testing with an open-face filter pack sampler, the denuder system was found to minimize positive gas adsorption artifacts caused by the adsorption of gaseous DC to quartz filter fiber (QFF) surfaces. In the denuder sampler, negligible amounts of DC were observed on a QFF placed downstream of a particle-loaded QFF, suggesting that DC detected on the backup QFF in the filter pack sampler resulted primarily from the adsorption of ambient G-phase DC rather than DC evaporated from particles collected on the front filter. Equations are presented for the evaluation of the magnitude of positive and negative sampling artifacts. Analysis of these equations indicates that the mass of DC evaporated from filter-bound particles present downstream of a denuder depends on (i) the volume of DC-free gas passed through the filter, (ii) the P-phase concentration and the PIG partition coefficients (K{sub}p) of the compounds comprising the P-phase DC, (iii)the temperature (T) (values of K{sub}p are inversely proportional to T), and (iv) the mass fraction of carbon in the compounds comprising P-phase DC. For these reasons, the magnitude of evaporative losses of DC in denuder samplers may vary among different sampling events. In addition, a method utilizing gas chromatography/mass spectrometry has been developed for determination of inertial impactor collection efficiency and denuder particle transmission efficiency. Using this method, only a single extraction of the sampler components is necessary, thereby reducing the number of extractions and analyses over conventional approaches by at least a factor of 2.
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