The crystals of Pt(S2COEt)2are orthorhombic, Pbca, with (at 20°C)a=7.799(3),b=7.368(6),c=20.588(7) Å.Dcale=2.46g cm−3forZ=4. The platinum atom resides on a crystallographic center of inversion and is bound to the four sulfur atoms of the xanthato ligand in a square planar geometry. The Pt−S distances are 2.313(6) and 2.320(7)Å with an intraligand S−Pt−S angle o
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