A comparative study of the chemical structures of sooting, atmospheric-pressure, laminar, flat-flames of CH3Cl/CH4were investigated using micro-probe sampling coupled with on-line mass spectrometry. In the presence of chlorine, the earlier and more abundant formation of CO, C2H2and C2H4were noted. The major reaction pathways responsible for the destruction of the fuels, and the formation and destruction of some of the intermediates are discussed.
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