AbstractEffect of temperature on the electrical conductivity of PVC‐copper composites has been studied. The temperature coefficient of dc resistivity of composites with fillers containing negligible oxide content in the range of 77–303 K is positive, indicating metallic‐type conduction. The temperature coefficient of dc resistivity of composites with fillers containing intermediate level of oxide at higher temperatures is negative, indicating a semiconducting behavior. Plots of log conductivity versus log frequency for composites in the insulating region show the hopping‐type con
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