Halogen-bridged cationic complexes of the type {CpM(CO)(3)}(2)XSbF6 (M = Mo, W; X = Cl, I), {CpW(CO)(2)Cl-2}(2)ClSbCl6, and the trichloride CpW(CO)(2)Cl-3

Lorenz IP.; Noth H.; Schneider R.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Halogen-bridged cationic complexes of the type {CpM(CO)(3)}(2)XSbF6 (M = Mo, W; X = Cl, I), {CpW(CO)(2)Cl-2}(2)ClSbCl6, and the trichloride CpW(CO)(2)Cl-3

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Halogen-bridged cationic complexes of the type {CpM(CO)(3)}(2)XSbF6 (M = Mo, W; X = Cl, I), {CpW(CO)(2)Cl-2}(2)ClSbCl6, and the trichloride CpW(CO)(2)Cl-3

机译：Halogen-bridged cationic complexes of the type {CpM(CO)(3)}(2)XSbF6 (M = Mo, W;X = Cl， I）、{CpW（CO）（2）Cl-2}（2）ClSbCl6 和三氯化物 CpW（CO）（2）Cl-3

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The reaction of CpMo(CO)(3)X (X = Cl, I) with SbF5 in toluene leads to the cationic, halogen bridged compounds {CpMo(CO)(3)}(2)XSbF6 (1, 2). CpW(CO)(3)Cl reacts with SbF5 to yield {CpW(CO)(3)}(2)ClSbF6 (3), whereas with SbCl5, the oxidative substitution product {CpW(CO)(2)Cl-2}(2)ClSbCl6 (4) is formed, which decomposes in solution to yield the trichloride CpW(CO)(2)Cl-3 (5). The strong Lewis acid SbF5 separates the halide from CpM(CO)(3)X (M = Mo, W), and the resulting cationic fragment "CpM(CO)(3)(+)" reacts with a further CpM(CO)(3)X forming a halonium bridge (1-3). The exclusive formation of SbF6- can be explained by the oxidizing power of SbF5. The IR, MS and NMR spectra of the compounds 1-5 as well as the X-ray structure analysis of 5 are reported and discussed. References: 17

机译：甲苯中 CpMo（CO）（3）X （X = Cl， I）与 SbF5 的反应导致阳离子卤素桥接化合物 [{CpMo（CO）（3）}（2）X]SbF6 （1， 2）。CpW（CO）（3）Cl 与 SbF5 反应生成 [{CpW（CO）（3）}（2）Cl]SbF6 （3），而与 SbCl5 形成氧化取代产物 [{CpW（CO）（2）Cl-2}（2）Cl]SbCl6 （4），在溶液中分解生成三氯化物 CpW（CO）（2）Cl-3 （5）。强路易斯酸 SbF5 将卤化物与 CpM（CO）（3）X （M = Mo， W）分离，得到的阳离子片段“CpM（CO）（3）（+）”与进一步的 CpM（CO）（3）X 反应形成钍桥（1-3）。SbF的排他性形成6- 可以用 SbF 的氧化能力来解释5.报告并讨论了化合物1-5的红外、质谱和核磁共振谱图以及5化合物的X射线结构分析。[参考文献： 17]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2000年第9期|1958-1962|共5页
作者
Lorenz IP.; Noth H.; Schneider R.;
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Univ Munich, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany.;

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正文语种英语
中图分类化学;
关键词
Organometallated halonium salts; Halogen bridges; Chloro complexes; Molybdenum complexes; Tungsten complexes;

机译：有机金属化钍盐;卤素桥;氯络合物;钼配合物;钨配合物;

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1. Halogen-bridged cationic complexes of the type [{CpM(CO)(3)}(2)X]SbF6 (M = Mo, W; X = Cl, I), [{CpW(CO)(2)Cl-2}(2)Cl]SbCl6, and the trichloride CpW(CO)(2)Cl-3 [J] . Lorenz IP., Noth H., Schneider R. Zeitschrift fur Anorganische und Allgemeine Chemie . 2000,第9期

机译：[{CpM（CO）（3）}（2）X] SbF6（M = Mo，W; X = Cl，I），[{CpW（CO）（2）Cl-2 }（2）Cl] SbCl6和三氯化物CpW（CO）（2）Cl-3
2. QUADRUPLY BONDED COMPLEXES CONTAINING BRIDGING ACETATE AND ETA(3)-PHOSPHINE LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF MO-2(OAC)CL-3(ETA(3)-TETRAPHOS-2) AND MO-2(OAC)CL-3(ETA(3)-ETP) (TETRAPHOS-2 EQUALS P(CH(2)CH(2)PPH3) ETP EQUALS PH(2)P [J] . Lee CT., Chen CT., Chen JD.Hsiao CD.Chiang SF. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1996,第10期

机译：QUADRUPLY BONDED COMPLEXES CONTAINING BRIDGING ACETATE AND ETA(3)-PHOSPHINE LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF MO-2(OAC)CL-3(ETA(3)-TETRAPHOS-2) AND MO-2(OAC)CL-3(ETA(3)-ETP) (TETRAPHOS-2 EQUALS P(CH(2)CH(2)PPH3) ETP EQUALS PH(2)P
3. Diphenyldichlorophosphonium trichloride-chlorine solvate 1 : 1, PPh2Cl2Cl-+(3)-center dot Cl-2: An ionic form of diphenyltrichlorophosphorane. Crystal structures of PPh2Cl2Cl-+(3)-center dot Cl-2 and (PPh2Cl2)(+)(2)InCl5(2-) [J] . Taraba J., Zak Z. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第11期

机译：Diphenyldichlorophosphonium trichloride-chlorine solvate 1 : 1, PPh2Cl2Cl-+(3)-center dot Cl-2: An ionic form of diphenyltrichlorophosphorane. Crystal structures of PPh2Cl2Cl-+(3)-center dot Cl-2 and (PPh2Cl2)(+)(2)InCl5(2-)
4. Evaluation Report on CCTF Core-I Reflood Tests Cl-2 (Run 11) and Cl-3 (Run 12). Effects of Initial Superheat of the Downcomer Wall [R] . Akimoto, H., Murao, Y. 1983

机译：关于CCTF Core-I Reflood的评估报告测试Cl-2（运行11）和Cl-3（运行12）。降液管壁初始过热的影响

Halogen-bridged cationic complexes of the type {CpM(CO)(3)}(2)XSbF6 (M = Mo, W; X = Cl, I), {CpW(CO)(2)Cl-2}(2)ClSbCl6, and the trichloride CpW(CO)(2)Cl-3

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