Multi-component coordination-driven self-assembly toward heterometallic macrocycles and cages

Li Hao; Yao Zi-Jian; Liu DongJin Guo-Xin

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Multi-component coordination-driven self-assembly toward heterometallic macrocycles and cages

机译：Multi-component coordination-driven self-assembly toward heterometallic macrocycles and cages

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摘要

Multi-component coordination-driven self-assembly has emerged as a promising research area of supramolecular chemistry for its ability to form systems with enhanced complexity. This review focuses on the synthesis of heterometallic macrocycles and cages. The synthetic strategy of heterometallic systems can be summarized into four categories: the hard-soft acid-base (HSAB) approach, the spatial regulating approach, the (semi-)macrocyclic stabilizing approach and the chelation-reinforced directing approach. Functional explorations into the heterometallic systems are also reviewed, especially for enzyme-mimicking catalysis. (C) 2014 Elsevier B.V. All rights reserved.

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来源
《Coordination chemistry reviews》 |2015年第6期|139-157|共19页
作者
Li Hao; Yao Zi-Jian; Liu DongJin Guo-Xin;
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作者单位

Fudan Univ, Dept Chem, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种英语
中图分类无机化学;
关键词
Coordination-driven self-assembly; Heterometallic macrocycles/cages; Artificial enzyme; Supramolecular catalysis;

Multi-component coordination-driven self-assembly toward heterometallic macrocycles and cages

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