SYNTHESIS AND STRUCTURE OF RE-4(MU(3)-TE)(4)(TEBR2)(4)BR-8 German

Lang ES.; Stahle J.; Abram U.

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SYNTHESIS AND STRUCTURE OF RE-4(MU(3)-TE)(4)(TEBR2)(4)BR-8 German

机译：RE-4（MU（3）-TE）（4）（TEBR2）（4）BR-8的合成与结构德语

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Re-4(mu(3)-Te)(4)(TeBr2)(4)Br-8 is obtained from the elements at 550 degrees C in an evacuated glass ampoule. The diamagnetic compound forms air-stable, metallic lustre black crystals crystallizing in the tetragonal space group I (4) over bar with a = 1120.2(2), c = 1393.5(3) pm, and Z = 2. The crystal structure is built up by isolated cluster molecules Re-4(mu(3)-Te)(4)(TeBr2)(4)Br-8 occupying the centres (4) over bar at 1/2, 1/2, 0 and 0, 0, 1/2. The inner sceleton is formed by a Re4Te4 heterocubane unit with short Re-Re distances of 277 and 283 pm, which can be discussed as single bonds. Each Re atom coordinates in addition two Br- ligands and one TeBr2 molecule. For Re therefore results the oxidation state +IV. Reaction of Re-4(mu(3)-Te)(4)(TeBr2)(4)Br-8 with I-2 yields (TeI4)(4). References: 18

机译：Re-4（mu（3）-Te）（4）（TeBr2）（4）Br-8 是在 550 °C 的真空玻璃安瓿中从元素中获得的。抗磁性化合物在四方空间群 I （4）中形成空气稳定的金属光泽黑色晶体，在 a = 1120.2（2）、c = 1393.5（3） pm 和 Z = 2 的四方空间群中结晶。晶体结构由孤立的团簇分子 Re-4（mu（3）-Te）（4）（TeBr2）（4）Br-8 在 1/2、1/2、0 和 0、0、1/2 处占据中心（4）构建。内部 sceleton 由一个 Re4Te4 异质 Bufferane 单元形成，其 Re-Re 距离较短，分别为 277 和 283 pm，可以作为单键进行讨论。每个 Re 原子此外配位两个 Br- 配体和一个 TeBr2 分子。因此，对于 Re，氧化态为 +IV。Re-4（mu（3）-Te）（4）（TeBr2）（4）Br-8与I-2的反应产率（TeI4）（4）.[参考资料： 18]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1996年第2期|251-253|共3页
作者
Lang ES.; Stahle J.; Abram U.;
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作者单位

UNIV TUBINGEN INST ANORGAN CHEM MORGENSTELLE 18 D-72076 TUBINGEN GERMANY;

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正文语种德语
中图分类化学;
关键词
Rhenium tellurium cluster compound; Re4te4 heterocuban; Crystal structure; Chemistry; Tellurium; Clusters;

机译：碲铼团簇化合物;Re4te4 heterocuban;晶体结构;化学;碲;集群;

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1. ChemInform Abstract: Synthesis and Crystal Structure of Re2Br4(Te2)(TeBr)2(TeBr2)2, a Dinuclear Complex with Te22‐, TeBr‐, and TeBr2Ligands. [J] . Johannes Beck, Klaus Mueller‐Buschbaum Chem Inform . 1999,第27期

机译：ChemInform Abstract: Synthesis and Crystal Structure of Re2Br4(Te2)(TeBr)2(TeBr2)2, a Dinuclear Complex with Te22‐, TeBr‐, and TeBr2Ligands.
2. NEW TYPE OF POLYMERIC INDIUM TELLURIDES - LOW-TEMPERATURE SYNTHESIS AND STRUCTURE CHARACTERIZATION OF M(EN)(3)IN2TE6 (M=FE, ZN) AND ALPHA- AND BETA-MO-3(EN)(3)(MU(2)-TE-2)(3)(MU(3)-TE)(MU(3)-O)IN2TE6 [J] . Li J., Emge TJ., Proserpio DM.Chen Z. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第7期

机译：NEW TYPE OF POLYMERIC INDIUM TELLURIDES - LOW-TEMPERATURE SYNTHESIS AND STRUCTURE CHARACTERIZATION OF M(EN)(3)IN2TE6 (M=FE, ZN) AND ALPHA- AND BETA-MO-3(EN)(3)(MU(2)-TE-2)(3)(MU(3)-TE)(MU(3)-O)IN2TE6
3. ChemInform Abstract: Synthesis and Structure of Re4(μ3‐Te)4(TeBr2)4Br8. [J] . E. SCHULZ LANG, U. ABRAM, J. STRAEHLE Chem Inform . 1996,第20期

机译：ChemInform Abstract: Synthesis and Structure of Re4(μ3‐Te)4(TeBr2)4Br8.
4. Robust Attitude Control Design of Quad-Tilt-Wing UAV: A Structured $mu$-Synthesis Approach [C] . Simone Panza, Masayuki Sato, Marco Lovera, IEEE Conference on Control Technology and Applications . 2018

机译：Quad-Tilt-Wing UAV的强大姿态控制设计：A结构化 $ MU $ -Synthesis方法
5. TE-domestication and horizontal transfer in a putative Nef-AP1mu mimic of HLA-A cytoplasmic domain re-trafficking [O] . Joseph S. Murray, Elaina H. Murray 2016

机译：在HLA-A细胞质域重新贩运的推定Nef-AP1mu模拟物中进行TE驯化和水平转移
6. Syntheses and Crystal Structures of Phenyltrimethylammonium Salts of Hexachlorotellurate(IV), C6H5(CH3)3N2TeCl6, catena-poly(Di-mu-chlorobis{tetrachlorotellurate(IV)})-mu-bromine, C6H5(CH3)3N2nTe2Cl10.Br2n and Di-mu-chlorobis{tetrachlorotellurate(IV)} catena-poly(mu-chlorobis{pentachlorotellurate(IV)})-mu-iodine(I), C6H5(CH3)3N4nTe2Cl10nTe2Cl11.In. [O] . Sverre Hauge, Kjartan Marøy, Jorma Antero Eloranta, 1996

机译：六氯酰氨酸甲酸酯（IV），C6H5（CH3）3N 2 TECL6，Catena-Poly （Di-Mu-chorobis（四氯酰脲（四）}） - Mu-溴，C6H5的合成和晶体结构（CH3）3N 2N和DI-MU-氯多菌（Tetrachlorotellurate（IV）} Catena-poly （mu-chorobis {pentachlorothurate（iv）） - mu-碘（i），C6H5 （CH3）3N 4N TE2CL11.I n。

SYNTHESIS AND STRUCTURE OF RE-4(MU(3)-TE)(4)(TEBR2)(4)BR-8 German

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