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首页> 外文期刊>Corrosion: The Journal of Science and Engineering >Formation and Dissolution on the Anodic Oxide Film on Zirconium in Alcoholic Aqueous Solutions
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Formation and Dissolution on the Anodic Oxide Film on Zirconium in Alcoholic Aqueous Solutions

机译：Formation and Dissolution on the Anodic Oxide Film on Zirconium in Alcoholic Aqueous Solutions

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摘要

The dissolution behavior of the anodic oxide film formed in alcoholic aqueous solutions was studied. Results indicated the dissolution mechanism of the duplex oxide film followed a zero-order rate equation. The increase in methanol concentration in the formation medium (phosphoric acid H3POJ) resulted information of an oxide film that incorporated little phosphate ion and that dissolved at a low rate. The dissolution rate of the oxide film decreased with increasing methanol concentration in the dissolution medium. This was attributed to the increase in the viscosity of the medium, which led to a decrease in the diffusion coefficient of the dissolution product of the zirconium oxide film. Dissolution of the anodic oxide film also was investigated as a function of the chain length of alcohols.

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