ALKALI METAL MANGANESE SELENIDES AND TELLURIDES - SYNTHESIS, CRYSTAL AND SPIN STRUCTURES German

Bronger W.; Kanert M.; Muller P.Schmitz D.Hardtdegen H.

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ALKALI METAL MANGANESE SELENIDES AND TELLURIDES - SYNTHESIS, CRYSTAL AND SPIN STRUCTURES German

机译：碱金属锰硒化物和碲化物 - 合成、晶体和自旋结构德语

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The compounds Rb2Mn3Se4, Cs2Mn3Se4, Rb2Mn3Te4 and Cs2Mn3Te4 were synthesized by the reaction of alkali metal carbonates with chalcogen and Mn or MnCO3 in a stream of hydrogen charged with chalcogen. Structural investigations show that all compounds crystallize in isotypic atomic arrangements (Cs2Mn3S4-type, space group Ibam, Z = 4). Additionally neutron diffraction experiments were carried out and yielded the spin structures of Rb2Mn3Se4 and Cs2Mn3Se4 (Shubnikov space group Ibam'). The structural related selenides ALiMnSe(2) and ALiZnSe(2) (A = K, Rb or Cs) were synthesized by analogous reactions. All these compounds are isotypic and crystallize in the BaZn2P2-structure type. References: 7

机译：以碱金属碳酸盐与硫族化合物和Mn或MnCO3反应合成了化合物Rb2Mn3Se4、Cs2Mn3Se4、Rb2Mn3Te4和Cs2Mn3Te4。结构研究表明，所有化合物都以同型原子排列（Cs2Mn3S4型，空间群Ibam，Z=4）结晶。此外，还进行了中子衍射实验，并得到了Rb2Mn3Se4和Cs2Mn3Se4（Shubnikov空间群Ibam'）的自旋结构。通过类似反应合成了结构相关的硒化物ALiMnSe（2）和ALiZnSe（2）（A = K，Rb或Cs）。所有这些化合物都是同型的，并以 BaZn2P2 结构型结晶。[参考文献： 7]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1996年第2期|313-318|共6页
作者
Bronger W.; Kanert M.; Muller P.Schmitz D.Hardtdegen H.;
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RHEIN WESTFAL TH AACHEN INST ANORGAN CHEM D-52056 AACHEN GERMANY;

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正文语种德语
中图分类化学;
关键词
Alkali metal manganese selenides; Alkali metal manganese tellurides; Crystal structure; Spin structure; Thiomanganates;

机译：碱金属硒化锰;碱金属碲化锰;晶体结构;自旋结构;硫锰酸盐;

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1. ChemInform Abstract: Alkali Metal Manganese Selenides and Tellurides ‐ Synthesis, Crystal and Spin Structures. [J] . W. BRONGER, H. HARDTDEGEN, M. KANERTP. MUELLERD. SCHMITZ Chem Inform . 1996,第20期

机译：ChemInform Abstract: Alkali Metal Manganese Selenides and Tellurides ‐ Synthesis, Crystal and Spin Structures.
2. First crystal structure of a (mu-oxamidato)tricopper(II)metal(II)-type tetranuclear complex: Synthesis, crystal structure, and magnetism of a copper(II)manganese(II) complex ((Cu3MnII)-Mn-II(mu-L)(3)(N-3)(2)center dot EtOH) incorporating a macrocyc [J] . Tang JK., Wang QL., Gao EQ.Chen JT.Liao DZ.Jiang ZH.Yan SP.Cheng P. Helvetica chimica acta . 2002,第1期

机译：First crystal structure of a (mu-oxamidato)tricopper(II)metal(II)-type tetranuclear complex: Synthesis, crystal structure, and magnetism of a copper(II)manganese(II) complex ((Cu3MnII)-Mn-II(mu-L)(3)(N-3)(2)center dot EtOH) incorporating a macrocyc
3. SYNTHESIS AND CRYSTAL STRUCTURE OF A NOVEL COPPER(I) CROWN COMPLEX - A SPECTROCHEMICAL METAL ION PROBE FOR ALKALI METAL AND ALKALINE EARTH METAL CATIONS [J] . Yam VWW., Cheung KK., Lo KKW. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第16期

机译：SYNTHESIS AND CRYSTAL STRUCTURE OF A NOVEL COPPER(I) CROWN COMPLEX - A SPECTROCHEMICAL METAL ION PROBE FOR ALKALI METAL AND ALKALINE EARTH METAL CATIONS
4. The effects of alkali metal on structure of manganese oxide supported on SBA-15 for application in the toluene catalytic oxidation [O] . Qu Zhenping, Bu Yibin, Qin Yuan, 2012

机译：The effects of alkali metal on structure of manganese oxide supported on sBa-15 for application in the toluene catalytic oxidation

ALKALI METAL MANGANESE SELENIDES AND TELLURIDES - SYNTHESIS, CRYSTAL AND SPIN STRUCTURES German

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