A series of anion-cation organobentonite are prepared by incorporating both cationic surfactant bromide dodecyltrimethylammonium (DTMAB) and anionic surfactant sodium dodecyl sulfate (SDS) to bentonite. The results indicate that the organic carbon contents of the organobentonites are proportional to the amounts of anionic and cationic surfactants in bentonite. The amount of organic pollutant removed from water depends greatly on the amount of SDS and DTMAB in the bentonite. Partition and adsorption contributions to the sorption amount of p-nitrophenol on organobentonites are described quantitatively. The mixed surfactants on anion-cation organobentonites excellently created partition mediums for organic pollutants in water. The removal rate of organic pollutants from water is improved by synergistic solubilization in both anionic and cationic surfactant moieties of the organobentonites. The effect of synergistic solubilization results mainly from partition at higher concentrations or adsorption at lower concentrations.
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