Chloroform was used as a model chlorocarbon system with high Cl/H ratio to investigate the thermal decomposition processes of chlorocarbons in pyrolytic reaction environments. The thermal decomposition of 1.0 chloroform in argon bath gas was studied to determine important chlorocarbon reaction pathways in pyrolysis. The reactions were studied in tubular flow reactors at a total pressure of 1 atm with residence times of 0.3-2.0 sec in the temperature range 535-800#xB0;C.
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