The title compound was synthesized by CS2insertion in the C-M bonds of the corresponding AgLi “ate” organomental compound. It contains flattened tetrahedral Ag4units, connected in polymeric chains by intermolecular Ag...S interactions. Two Ag atoms and three S atoms are in a distorted square pyramidal arrangement around each silver atom. The crystals are tetragonal, space group 141/a witha=23.706(2) andc=12.934(2) Å. The structure was refined toR=0.032 for 889 reflect
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