AbstractStructural studies of oligobutadienediol‐based polyurethanes with various degrees of crosslinking were carried out. From absolute small‐angle X‐ray scattering, the degree of segregation of components was determined. It was concluded that a complete microphase separation of the different components is realized in all samples irrespective of the degree of crosslinking, and these polymers are two‐phase systems. While stretching, the fibrillar structure is
展开▼