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Nature of the Rigidhyphen;Rod Mesophase

机译:Nature of the Rigidhyphen;Rod Mesophase

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The thermodynamic phases of the rigidhyphen;rod gas are rehyphen;examined. Introduced in its present form by Zwanzig, the model postulates elongated molecules of parallelepiped shape with only three allowed orientations (mutually perpendicular). We have added to the virial series the cluster integrals represented by eighthyphen;point bicolored graphs. It is demonstrated that the Padeacute; approximants generated by the truncated cluster expansion provide a much more stable sequence of parameters characterizing the isotropicndash;anisotropic phase transition. It is similarly shown that there are no stable phases predicted for which the orientational distribution is not axially symmetric. The relative volume change accompanying the transition is still predicted to be larger than that observed in the isotropicndash;nematic liquid crystal transition.

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