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Microstructure and mechanical properties of zirconia-toughened lithium disilicate glass-ceramic composites

机译:Microstructure and mechanical properties of zirconia-toughened lithium disilicate glass-ceramic composites

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The lithium disilicate glass-ceramics composites reinforced and toughened by tetragonal zirconia (3Y-TZP) were prepared by hot-pressing at 800 degrees C with varying zirconia content from 0 to 30 wt.. In the case of the composites of small zirconia content (below 10 wt.), zirconia acted as nucleation agent primarily, and the microstructure was refined continuously. The morphology of Li2Si2O5 crystals transformed from rod-shaped to spherical structure, and the mechanical properties decreased inevitably. For the composites of large zirconia content (from 15 wt. to 30 wt.), however, zirconia restrained the phase separation of glass. The morphology of Li2Si2O5 crystals transformed to rod-shaped structure again. The mechanical properties of the composite at zirconia content of 15 wt. increased up to 340 MPa and 3.5 MPa m(1/2) which were much higher than those of zirconia-free glass-ceramics. The improved properties were attributed mainly to compressive stress reinforcement, phase transformation and bridging toughening mechanisms. (C) 2013 Published by Elsevier B.V.

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