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>Nearhyphen;resonant electronic energy transfer: Initial rotational state populations of NO(Athinsp;2Sgr;+,vprime;=0,1) produced by energy transfer from Zn(1P1)
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Nearhyphen;resonant electronic energy transfer: Initial rotational state populations of NO(Athinsp;2Sgr;+,vprime;=0,1) produced by energy transfer from Zn(1P1)
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机译：Nearhyphen;resonant electronic energy transfer: Initial rotational state populations of NO(Athinsp;2Sgr;+,vprime;=0,1) produced by energy transfer from Zn(1P1)
The complete initial distribution of product vibrational and rotational state populations for the following energy transfer process has been determined for Boltzmann conditions at sim;550deg;K.: The initial population distribution of NO(Athinsp;2Sgr;+,vprime;=1) rotational levels is remarkably consistent with that predicted by the Crossndash;Gordon version of nearhyphen;resonant dipolendash;dipole theory, except that a minor (sim;7percnt;) Boltzmannhyphen;like population must be included for satisfactory simulation of the sensitized NO ggr; (1,X) band spectra in the frequency regions dominated by transitions originating from lower rotational levels. The initial rotational level population distribution of NO (Athinsp;2Sgr;+,vprime;=0) is very similar to a Boltzmann population distribution at sim;1400deg;K. The rate of production of NO(Athinsp;2Sgr;+,vprime;=1) is sim;10 times that of NO(Athinsp;2Sgr;+,vprime;=0). Efficient rsquo;rsquo;nearhyphen;resonantrsquo;rsquo; dipolendash;dipole interactions appear, therefore, to constitute the dominant mechanism for electronic energy transfer in this particular system. Production of NO(Athinsp;2Sgr;+,vprime;=0), and possibly the lower rotational levels of NO(Athinsp;2Sgr;+,vprime;=1), likely result from a minor competing mechanism. A Zn+NOminus;chargehyphen;transfer surface crossing is suggested as one possibility.
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